Properties of Water

We have water around us every day, and we think of it as quite normal. But water is not a normal liquid, it is an extremely special and unusual liquid. What are some of the special properties of water?

Water melts at a very high temperature, it also boils at a very high temperature and it is stable as a liquid over a very large temperature range, see the table below. You might not think melting at 0 °C as a "high" temperature, but compared to other similar molecules it is very high!

Water is the only substance to exist in all three states, as a gas, liquid and solid under normal conditions (pressures of 1 atm and temperatures around 25 °C)

Let's make some comparisons.

H2S is very similar to water in chemical make-up, S (sulphur) lies just below oxygen on the periodic table.

  • H2S melts at -85 °C, compared to water's 0 °C
  • H2S is a gas at normal temperature and pressure, while water is a liquid
  • H2S is only liquid for ≈24 °C, while water is liquid for 100 °C
NH3 is a small molecule (like water) that can form H-bond networks, however NH3 can only form one H-bond.

  • NH3 melts at -78 °C, compared to water's 0 °C
  • NH3 is a gas at normal temperature and pressure, while water is a liquid
  • NH3 is only liquid for ≈45 °C, while water is liquid for 100 °C
molecule mp °C bp °C liquid
range
ambient state
H2O 0 100 100 liquid
H2S -85 -61 24 gas
NH3 -78 -33 45 gas
mp=melting point, bp=boiling point,
ambient means "normal" pressure and temperature, ie 1atm and 25 °C

How does water do this?

The H-bonds in water hold the water molecules together, put another way water is "sticky" at the molecular level. This means water "likes" to be a liquid, the water molecules want to stick together, thus water has a large liquid range. H-bonding also means we have to add a lot of energy into the system to force the water molecules to seperate, that is we have to heat it to a higher temperature before we can turn liquid water into a gas (ie boil the jug!); water has a high melting point and a high boiling point (compared to other similar molecules).


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